A week or so ago, I made my fall picks.... my buddy Jay, though, is way more into the TV and Film industry than I am (want to know who's got the 18-49 demo for Monday 9-9:30? he can tell you).
He did a great job this year with his annual fall preview. Check it out, it's a great side-by-side comparison, with predictions for what will succeed and fail, etc.
I suggest filling your empty 9-10 slot on Sundays with Alias.
Realistically my Sunday 9-10 is usually filled with "whatever HBO is showing at any given time".